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Attivitŕ di ricerca
Research activities

Environmental Heterogeneous Catalysis and Nanomaterials

PUBLICATIONS


  1. J. Kašpar, R. Spogliarich, G. Mestroni and M. Graziani, "Water Gas Shift Reaction Homogeneously Catalyzed by [Ir(diene)L2]+ Complexes", J.Organometal.Chem., 208, C15 (1981).
  2. R. Spogliarich, G. Zassinovich, J.Kašpar and M. Graziani, "Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Iridium(I) Complexes", J.Mol.Catal., 16, 359 (1982).
  3. J. Kašpar, R. Spogliarich and M. Graziani, "Hydrogen Transfer Reactions Catalyzed by Rhodium(III) and Iridium(III)-Tin(II) Systems", J.Organometal.Chem., 231, 71 (1982).
  4. R. Spogliarich, A. Tencich, J. Kašpar and M. Graziani, "Hydrogenation of Ketones and Olefins via Hydrogen Transfer Reaction Catalyzed by Rhodium and Iridium Phosphine Complexes", J.Organometal.Chem., 240, 453 (1982).
  5. J. Kašpar, R. Spogliarich, A. Cernogoraz and M. Graziani, "Homogeneous Catalytic Reduction of Benzalacetone with CO and H2O", J.Organometal.Chem., 255, 371 (1983).
  6. M. Visintin, R. Spogliarich, J. Kašpar and M. Graziani, "Selective Reduction of Unsaturated Ketones to Unsaturated Alcohols Catalyzed by an Iridium-Phosphine System", J.Mol.Catal., 24, 277 (1984).
  7. J. Kašpar, R. Spogliarich and M. Graziani, "Selective Reduction of Dienes to Monoenes via Hydrogen Transfer Reaction in the Presence of Carbonyl Clusters", J.Organometal.Chem., 281, 299 (1985).
  8. R. Spogliarich, J. Kašpar, M. Graziani, F. Morandini and O. Piccolo, "Asymmetric Transfer Hydrogenation of Acetophenone with Rhodium(I) Complexes Containing Chiral Diphosphines", J.Catal., 94, 292 (1985).
  9. M. Visintin, R. Spogliarich, J. Kašpar and M. Graziani "Selective Reduction of a,b Unsaturated Aldehydes Catalyzed by Iridium Phosphines Systems". J.Mol.Catal., 32, 349, (1985).
  10. R. Spogliarich, F. Morandini, J. Kašpar and M. Graziani "Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Rhodium(I) and Iridium(I) Complexes", J.Organometal. Chem., 306, 407, (1986).
  11. E. Farnetti, M. Pesce, J. Kašpar, R. Spogliarich and M. Graziani "Hydrogenation of a,b Unsaturated Aldehydes and Ketones Catalyzed by Hydridoiridium Phosphine Complexes", J.C.S.Chem.Commun., 746, (1986).
  12. M. Lenarda, R. Ganzerla, J. Kašpar and M. Graziani, "Catalysis by Mono and Polynuclear Compounds Supported on Zeolites", in Homogeneous and Heterogeneous Catalysis, 999, (1986), Yu.Yermakov, V.Likholobov eds., VNU Science Press, Utrecht, The Netherlands.
  13. E. Farnetti, M. Pesce, J. Kašpar, R. Spogliarich and M. Graziani, "Selective Hydrogenation of Cinnamic Aldehyde to Unsaturated Alcohol Catalyzed by Iridium Phosphine Systems", J.Mol.Catal., 43, 35 (1987).
  14. E. Farnetti, J. Kašpar, R. Spogliarich and M. Graziani, "Selective Hydrogenation of PhCH=CHCOCH3 to Unsaturated Alcohol Catalyzed by H3IrP3", J.Chem.Soc.Dalton, 947, (1988).
  15. M. Lenarda, J. Kašpar, R. Ganzerla, A. Trovarelli and M. Graziani, "Water Gas Shift Reaction Catalyzed by Osmium Carbonyls Supported on Zeolites", J.Catal., 112, 1 (1988).
  16. J. Kašpar, A. Trovarelli, M. Graziani, C. Dossi, R. Psaro, R. Ugo, G.M. Zanderighi, M. Lenarda and R. Ganzerla, "Hydrogen Transfer Reduction of Hexan-2-one Catalyzed by a Silica Surface Grafted Osmium Cluster", J.Mol.Catal., 44, 183 (1988).
  17. J. Kašpar, A. Trovarelli, G. Dolcetti and M. Graziani, "Silica Supported Ruthenium and Osmium Carbonyls as Catalysts for Cycloocta-1,5-diene Isomerization", J.Mol.Catal., 48, 29 (1988).
  18. R. Spogliarich, E. Farnetti, J. Kašpar, M. Graziani and E. Cesarotti, "Selective Hydrogenation of Benzilideneacetone Catalyzed by Iridium Diphosphine Complexes", J.Mol.Catal., 50, 19 (1989).
  19. J. Kašpar, A. Trovarelli, M. Graziani, C. Dossi, R. Psaro, R .Ugo, A. Fusi, M. Lenarda and R. Ganzerla, "A Molecular Approach to Hydrogen Transfer Reduction of Ketones Catalyzed by a Silica Supported Osmium Cluster", J.Mol.Catal., 51, 181 (1989).
  20. J. Kašpar, A. Trovarelli, M. Lenarda, and M. Graziani, "A Meerwein- Ponndorf-Verley Type Reduction of a,b Unsaturated Ketones to Allylic Alcohols Catalyzed by MgO", Tetrahedron Letters, 30, 2705 (1989).
  21. J. Kašpar, M. Graziani, A. Trovarelli, and G .Dolcetti, "Groups 8 and 9 Metal Carbonyls as Catalysts for 1,5-Cyclooctadiene Isomerization", J.Mol.Catal., 55, 229 (1989).
  22. F. Demanins, M. Graziani, J. Kašpar, S. Modesti, F. Raicich, R. Rosei, F. Tommasini and A. Trovarelli, "Search for the Neutron Production in Niobium Deuteride", J.Solid State Commun., 71, 559 (1989).
  23. C. Ebert, T. Gianferrara, M. Graziani, J. Kašpar, P. Linda, and A. Trovarelli, "Application of Chemometrics to Heterogeneous Catalysis: Optimization of 1,4-Cyclo­octadiene Yield and Selectivity in the Isomerization of 1,5-Cyclooctadiene Catalyzed by Silica-Supported Ir4(CO)12", J.Catal., 124, 433 (1990).
  24. A. Trovarelli, C. Mustazza, G. Dolcetti, J. Kašpar and G. Dolcetti, "Carbon Dioxide Hydrogenation on Rhodium Supported on Transition Metal Oxides: Effects of Reduction Temperature on Product Distribution", Appl.Catal., 65, 129 (1990).
  25. E. Farnetti, J. Kašpar and M. Graziani, "Electron Rich Iridium Complexes. Metal-Basicity Controlled Chemoselectivity in Hydrogen Transfer Reductions.", J.Mol.Catal., 63, 5 (1990).
  26. A. Trovarelli, J. Kašpar, G. Dolcetti and M. Graziani, "A Kinetic Approach to the Problem of Reaction Yield Optimization: Isomerization of 1,5-Cyclooctadiene Catalyzed by Ir4(CO)12", J.Catal., 129, 288 (1991).
  27. A. Trovarelli, C. Malitesta, L. Sabbatini, S. Maschio and J. Kašpar, "A Multitechnique Analytical Characterisation of the Isomerisation Catalyst Ir4(CO)12 on Silica", Mater.Chem.Phys., 29, 405 (1991).
  28. J. Kašpar, A. Trovarelli, F. Zamoner, E. Farnetti and M. Graziani, "Chemosective Reduction of Enones to Allylic Alcohols",in Heterogeneous Catalysis and Fine Chemicals II, Elsevier, Amsterdam, Stud.Surf.Sci.Catal., 59, 253 (1991).
  29. M. Lenarda, R. Ganzerla, L. Storaro, A. Trovarelli, R. Zanoni and J. Kašpar, "Vapour Phase Hydroformylation of Ethylene and Propene Catalyzed by a Rhodium Containing Aluminum Pillared Smectite Clay", J.Mol.Catal., 72, 75 (1992).
  30. J. Kašpar, G. Picasso Escobar, A. Trovarelli, and M. Graziani, "Chemoselective Hydrogenation of Unsaturated Carbonyl Compounds over Group 8 and 9 Titania Supported Metal Catalysts". J.Mol.Catal., 72, 243 (1992).
  31. A. Trovarelli, G. Dolcetti, C. de Leitenburg, J. Kašpar, P. Finetti, and A. Santoni, "Rh-CeO2 Interaction Induced by High Temperature Reduction. Characterization and Catalytic Behaviour in Transient and Continuous Conditions", J.C.S.Faraday Trans., 88, 1311 (1992).
  32. C. Bianchini, M. Graziani, E. Farnetti, J. Kašpar, and F. Vizza "Molecular Solid-State Organometallic Chemistry of Tripodal- (polyphosphine)metal Complexes. Catalytic Hydrogenation of Ethylene at Iridium", J.Amer.Chem.Soc., 115, 1753 (1993).
  33. C. Bianchini, P. Frediani, M. Graziani, J. Kašpar, A. Meli, M. Peruzzini and F. Vizza, "Molecular Solid-Gas Organometallic Chemistry. Catalytic and Stoichiometric Transformations of Ethyne at Iridium", Organometallics, 12, 2886 (1993).
  34. C. Bianchini, F. Vizza, M. Graziani and J. Kašpar, "Molecular Solid-State Organometallic Chemistry of Tripodal-(polyphosphine)metal Complexes. Catalytic Hydrogenation of Ethylene at Iridium", in Advances in Catalyst Design II, 327, (1993), C.N.R.Rao and M.Graziani eds, World Scientific Publisher, Singapore.
  35. A. Trovarelli, G. Dolcetti, C. de Leitenburg, and J. Kašpar, "CO2 Hydrogenation over Platinum Group Metals Spported on CeO2: Evidence for a Transient Metal-Support Interaction" in New Frontiers in Catalysis, Elsevier, Amsterdam, Stud.Surf.Sci.Catal., 75 2781 (1993).
  36. J. Kašpar, C. de Leitenburg, P. Fornasiero, A. Trovarelli, and M. Graziani, "NO Reduction by CO over Rh/Al2O3. Effect of Rhodium Dispersion on the Catalytic Properties", J.Catal., 146, 136, (1994).
  37. G. Ranga Rao, J. Kašpar, R. di Monte, S.Meriani and M.Graziani, "NO Decomposition over Partially Reduced Metallized CeO2-ZrO2 Solid Solution", Catalysis Lett., 24, 107 (1994).
  38. C. Bianchini, M. Graziani, J. Kašpar, A. Meli, M. Peruzzini, and F. Vizza "Molecular Solid-Gas Organometallic Chemistry. Catalytic and Stoichiometric Iridium-Assisted C-C Bond-Forming Reactions Involving Ethyne and Ethene". Organometallics, 13, 1165, (1994),
  39. J. Kašpar, M. Graziani, A.M. Rahman, A. Trovarelli, E.J.S. Vichi and E.C. Silva, "Carbon Dioxide Hydrogenation over Iron Containing Catalysts", Appl.Catal.A: General, 117, 125 (1994).
  40. P. Fornasiero, R. Di Monte, G. Ranga Rao, J. Kašpar, S. Meriani and M. Graziani, "Rh-loaded CeO2-ZrO2 Solid Solutions As Highly Efficient Oxygen Exchangers: Dependence of the Reduction Behavior and the Oxygen Storage Capacity on the Structural Properties.", J.Catal., 151, 168 (1995).
  41. G. Ranga Rao, P. Fornasiero, J. Kašpar, S. Meriani, R. Di Monte and M. Graziani, "NO Decomposition over Partially Reduced Metallized CeO2 Containing Catalysts", Stud.Surf.Sci.Catal., 96, 631 (1995).
  42. C. Bianchini, M. Peruzzini E. Farnetti, J. Kašpar and M. Graziani, "Chemoselective Reduction of a,b Unsaturated Ketones Catalyzed by Transition Metal Complexes with Polydentate Ligands", J.Organomet.Chem., 488, 91 (1995).
  43. G. Balducci, P. Fornasiero, R. Di Monte, J. Kašpar, S. Meriani and M. Graziani, "An Unusual Promotion of the Redox Behaviour of CeO2-ZrO2 Solid Solutions upon Sintering at High Temperature", Catal.Lett., 33, 193 (1995).
  44. J. Kašpar, P. Fornasiero and M. Graziani, "Role of the Metal in the Automotive Catalytic Converters.", in Perspectives in Inorganic Chemistry, New Compounds and Materials, S.Daolio, E.Tondello, P.A.Vigato, SCI-Divisione Chimica Inorganica, Bressanone, vol.V, (1995), p.53.
  45. P. Fornasiero, G. Balducci, J. Kašpar, G. Vlaic, S. Meriani, R. Di Monte, and M. Graziani, "Metal-Loaded CeO2-ZrO2 Mixed Oxides as Innovative Automotive Exhaust Catalysts." in Enviromental Catalysis, G.Centi, C.Cristiani, P.Forzatti, S.Perathoner eds., SCI Publisher, Roma, (1995), p.383.
  46. P. Fornasiero, G. Balducci, J. Kašpar, S. Meriani, R. di Monte and M. Graziani, "Metal-Loaded CeO2-ZrO2 Solid Solutions as Innovative Catalysts for Automotive Catalytic Converters.", Catal.Today, 29, 47 (1996).
  47. G. Ranga Rao, P. Fornasiero, R. di Monte, J. Kašpar, G. Vlaic, G. Balducci, S. Meriani, G. Gubitosa, A. Cremona, and M. Graziani, "Reduction of NO over Partially Reduced Metal-loaded CeO2-ZrO2 Solid Solutions.", J.Catal., 162, 1 (1996).
  48. P. Fornasiero, G. Balducci, R. Di Monte, J. Kašpar, V. Sergo, G. Gubitosa, A. Ferrero, and M.Graziani, "Modification of the Redox Behaviour of CeO2 Induced by Structural Doping with ZrO2", J.Catal., 164, 173 (1996).
  49. P. Fornasiero, J. Kašpar, and M. Graziani, «Redox Behaviour of High Surface Area Rh-loaded Ce0.5Zr0.5O2 Mixed Oxide», J.Catal., 167 (1997) 576.
  50. C. de Leitenburg, A. Trovarelli, and J. Kašpar, «A Temperature Programmed and Transient Kinetic Study of CO2 Activation and Methanation over CeO2 Supported Noble Metals», J.Catal., 166 (1997) 98.
  51. G. Vlaic, P. Fornasiero, S. Geremia, J. Kašpar, and M. Graziani, " Relationship between the Zirconia-Promoted Reduction in the Rh-loaded CeO2-ZrO2 Mixed Oxide and Zr-O Local Structure ", J.Catal., 168 (1997) 386.
  52. G. Balducci, M.S. Islam, J.D. Gale, J. Kašpar, P. Fornasiero, and M. Graziani, "Computer Simulation Studies of Bulk Reduction and Oxygen Migration in CexZr1-xO2 Solid Solutions", J.Phys.Chem.B, 101 (1997) 1750.
  53. H. C.Long, M.L. Turner, P. Fornasiero, J. Kašpar, M. Graziani, and P.M. Maitlis, "Vinylic Initiation of the Fischer-Tropsch Reaction over Ruthenium on Silica Catalysts", J.Catal., 167 (1997) 172.
  54. P. Vidmar, P. Fornasiero, J. Kašpar, G. Gubitosa and M. Graziani, «Effects of Trivalent Dopants on the Redox Properties of Ce0.6Zr0.4O2 Mixed Oxide», J.Catal., 171 (1997) 160.
  55. G. Vlaic, R. Di Monte, P. Fornasiero, E. Fonda, J. Kašpar, and M. Graziani, »The CeO2-ZrO2 System: Redox Properties and Structural Relationships», Stud.Surf.Sci.Catal., 116 (1998) 185.
  56. R. Di Monte, J.Kašpar, P. Fornasiero, A. Ferrero, G. Gubitosa, and M. Graziani, «NO Reduction by CO over Pd/CeO2-ZrO2/Al2O3 Catalysts», Stud.Surf.Sci.Catal., 116, 559 (1998).
  57. R. Di Monte, P.Fornasiero, M.Graziani, and J.Kašpar, «Oxygen Storage and Catalytic NO Removal Promoted by CeO2-Containing Mixed Oxides», J.Alloys Comp., 275-277 (1998) 877.
  58. G. Balducci, J.Kašpar, P.Fornasiero, M.Graziani, and M.S.Islam, "Surface and Reduction Energetics of the CeO2-ZrO2 Catalysts", J.Phys.Chem.B, 102 (1998) 557.
  59. P. Fornasiero, G. Ranga Rao, J. Kašpar , F. L'Erario, and M. Graziani ,«Reduction of NO by CO over Rh/CeO2-ZrO2 Catalysts: Evidence for a Support Promoted Catalytic Activity», J.Catal., 175 (1998) 269.
  60. E. Bekyarova, P. Fornasiero, J. Kašpar , and M. Graziani, «CO Oxidation on Pd/CeO2-ZrO2», Catal.Today, 45 (1998) 179.
  61. G. Colon, M.Pijolat, F.Valdivieso, H.Vidal, J. Kašpar, E.Finocchio, M.Daturi, C.Binet and J.C.Lavalley, «Surface and Structural Characterization of CexZr1-xO2 Cezirencat Mixed Oxides as Potential TWC Promoters», J.Chem.Soc., Faraday Trans., (1998) 3717.
  62. M. Daturi, C.Binet, J.C.Lavalley, H.Vidal, J.Kašpar, M.Graziani and G.Blanchard, «Influence of the Activation Conditions of Residual Impurities on Ceria-Zirconia Mixed Oxides», J.Chim.Phys., Phys.-Chim. Biol., 95 (1998) 2048.
  63. P. Fornasiero, J. Kašpar, V.Sergo, and M. Graziani, «Redox Behaviour of High Surface Area Rh, Pt and Pd-loaded Ce0.5Zr0.5O2 Mixed Oxide», J.Catal., 182 (1999) 56.
  64. E. Finocchio, M. Daturi, C. Binet, J.C. Lavalley, F. Fally, V. Perrichon, H. Vidal, J. Kašpar, M. Graziani and G. Blanchard, «Oxygen Storage Capacity Improvement Using CeO2-ZrO2 Mixed Oxides in Three Way Catalysts», in "Science and Technology in Catalysis 1998", H. Hattori and K. Otsuka Eds., Kodansha Ltd., Tokyo, Stud.Surf. Sci. Catal., 121, 257 (1999).
  65. G. Vlaic, R. Di Monte, P. Fornasiero, E. Fonda, J. Kašpar, and M. Graziani, »Redox Property - Local Structural Relationships in the Rh-loaded CeO2-ZrO2 Mixed Oxides», J.Catal., 182 (1999) 378.
  66. S. Bernal, J. Kašpar and A. Trovarelli, editors of Special issue of Catalysis Today on «Recent Progress in Catalysis by Ceria and Related Systems», Catal.Today, 50 (1999) 1.
  67. J. Kašpar, P. Fornasiero and M. Graziani, «Use of CeO2-Based Oxides in the Three Way Catalysis», Catal.Today, 50 (1999) 285.
  68. J. Kašpar, P. Fornasiero and M. Graziani, «On the Rate Determining Step in the Reduction of CeO2-ZrO2 Mixed Oxides», Appl.Catal.B Environ., 22 (1999) L11.
  69. H. Vidal, S. Bernal, J. Kašpar, M. Pijolat, V. Perrichon, G. Blanco, J.M. Pintado, R.Baker, G. Colon and F. Fally, «Influence of High Temperature Treatments under Net Oxidizing and Reducing Conditions on the OSC and OBC Properties of a Ce0.68Zr0.32O2 Mixed Oxide», Catal. Today, 54 (1999) 93.
  70. P. Fornasiero, E. Fonda, R. Di Monte, G. Vlaic, J. Kašpar, and M. Graziani, »Relationships between Structural/Textural Properties and Redox Behavior in Ce0.6Zr0.4O2 Mixed Oxides», J.Catal., 187 (1999) 177.
  71. J. Kašpar, «Design of CeO2-ZrO2 mixed oxides as highly efficient oxygen storage systems for advanced three-way catalysts», in «Preparaciňn y Caracterizaciňn de Catalizadores», Reunion de la Sociedad Espanola de Catalisis, G.Blanco and C.Mira eds., Servizio de publicaciones, Univesidad de Cadiz, Cadiz (Spagna), ISBN 84-7786-557-4, pp.19-32 (1999).
  72. R. Di Monte, P. Fornasiero, J. Kašpar, P. Rumori, G. Gubitosa, and M. Graziani, «Pd/Ce0.6Zr0.4O2/Al2O3 as Advanced Materials for Three-way Catalysts. Part 1. Catalyst Characterisation, Thermal Stability and Catalytic Activity in the Reduction of NO by CO. », Appl.Catal.B Environ., 24 (2000) 157.
  73. J. Kašpar, M. Graziani, and P. Fornasiero, «Ceria-Containing Three Way Catalysts», "Handbook on the Physics and Chemistry of Rare Earths", K.A. Gschneidner, Jr. and L.Eyring, eds, Elsevier Science B.V., Amsterdam, vol. 29, ch. 184, pp. 159-267 (2000).
  74. P. Fornasiero, N. Hickey, J. Kašpar, C. Dossi, D. Gava, and M. Graziani, «Redox and Chemisorptive Properties of ex-chloride and ex-nitrate Rh/Ce0.6Zr0.4O2 Catalysts. Part 1: Effect of Low Temperature Redox Cycling», J.Catal., 189 (2000) 326.
  75. P. Fornasiero, N. Hickey, J. Kašpar, T. Montini, and M. Graziani, «Redox and Chemisorptive Properties of ex-chloride and ex-nitrate Rh/Ce0.6Zr0.4O2 Catalysts. Part 2: Effect of High Temperature Redox Cycling», J.Catal., 189 (2000) 339.
  76. P. Fornasiero, J. Kašpar, S. Fagotto, and M. Graziani «Nitric Oxide Promoted Partial Oxidation of Hydrocarbons under Strongly Oxidising Conditions», J.Catal., 189 (2000) 467.
  77. G. Balducci, M. Saiful Islam, J. Kašpar, P. Fornasiero, and M. Graziani, «Bulk Reduction and Oxygen Migration in the Ceria-Based Oxides», Chem.Mater., 12 (2000) 677.
  78. F. Fally, V. Perrichon, H. Vidal, J. Kašpar, G. Blanco, J.M. Pintado, S. Bernal, G. Colon, M. Daturi, J.C. Lavalley, «Modification of the Oxygen Storage Capacity of CeO2-ZrO2 Mixed Oxides after Redox Aging», Catal.Today, 59 (2000) 373.
  79. G. Vlaic, P. Fornasiero, G. Martra, E. Fonda, J. Kašpar, L. Marchese, E. Tomat, S. Coluccia, and M. Graziani, «Morphology of Rhodium particles in ex-chloride Rh/Ce0.5Zr0.5O2 Catalyst», J.Catal., 190 (2000) 182.
  80. P. Fornasiero, R. Di Monte, T. Montini, J. Kašpar, and M. Graziani, «Thermal Stability and Oxygen Storage Capacity of Noble Metal/Ceria-Zirconia Catalysts for the Automotive Converters with the On-Board-Diagnostics (OBD)», Stud.Surf.Sci.Catal., 130 (2000) 1355.
  81. H. Vidal, J. Kašpar, M. Pijolat, G. Colon, S. Bernal, A. Cordón, V. Perrichon and F. Fally, «Redox Behavior of CeO2-ZrO2 Mixed Oxides. I. Influence of Redox Cycling on High Surface Area Catalysts», Appl.Catal.B Environ., 27 (2000) 49.
  82. J. M. Gatica, R.T. Baker, P. Fornasiero, S. Bernal, G. Blanco, and J. Kašpar, «Rhodium Dispersion in a Rh/Ce0.68Zr0.32O2 Catalyst Investigated by HRTEM and H2 Chemisorption», J.Phys.Chem. B., 104 (2000) 4667.
  83. N. Hickey, P. Fornasiero, J. Kašpar, M. Graziani, G. Blanco and S. Bernal, «Significant room temperature oxygen storage over 0.58% Pt/Ce0.68Zr0.32O2 when H2 is used as a reducing agent», Chem. Commun., 357 (2000).
  84. M. Daturi, E. Finocchio, C. Binet, J.C. Lavalley, F. Fally, V. Perrichon, H. Vidal, N. Hickey and J. Kašpar, «Reduction of High Surface Area CeO2-ZrO2 Mixed Oxides», J.Phys.Chem.B, 104 (2000) 9186.
  85. G. Centi, P.Ciambelli, and J.Kašpar, « Le marmitte catalitiche inquinano? Una risposta dall'analisi dello stato dell'arte e degli sviluppi della ricerca in Europa ed Italia.», Chim.Ind., (2000) 631.
  86. R. Di Monte, P. Fornasiero, J. Kašpar, M. Graziani, J. M. Gatica, S. Bernal, and A. Gomez-Herrero. Stabilisation of nanostructured Ce0.2Zr0.8O2 solid solution by impregnation on Al2O3: a suitable way for production of thermally stable oxygen storage/release promoters for three-way catalysts”, Chem.Commun., 2167, (2000).
  87. N. Hickey, P. Fornasiero, R. Di Monte, J. Kašpar, M. Graziani, and G. Dolcetti, “A Comparative Study of Oxygen Storage Capacity over Ce0.6Zr0.4O2 mixed oxides investigated by Temperature Programmed Reduction and Dynamic-OSC measurements”, Catal.Lett., 72 (2001) 45.
  88. G. Centi, P. Fornasiero, M. Graziani, J. Kašpar, and F. Vazzana, «Enhancement of the low temperature activity in NO reduction in lean conditions by SMSI effect in Pt/ZrO2-CeO2 on Alumina catalyst», Top.Catal., 16/17 (2001) 173.
  89. J. Kašpar, R. Di Monte, P. Fornasiero, M. Graziani, H. Bradshaw, and C. Norman, «Dependency of the Oxygen Storage Capacity in Zirconia-Ceria Solid Solutions upon Textural Properties», Top.Catal., 16/17 (2001) 83.
  90. H. Vidal, J. Kašpar, M. Pijolat, G. Colon, S. Bernal, A. Cordón, V. Perrichon and F. Fally, «Redox Behavior of CeO2-ZrO2 Mixed Oxides. II. Influence of Redox Ageing on Low Surface Area Catalysts», Appl.Catal.B Environ., 30 (2001) 75.
  91. J. M. Gatica, R. T. Baker, P. Fornasiero, S. Bernal, and J. Kašpar, “Characterisation of the metal phase in NM/Ce0.68Zr0.32O2 (NM: Pt and Pd) catalysts by hydrogen chemisorption and HRTEM microscopy: a comparative study”, J.Phys.Chem. B, 105 (2001) 1191.
  92. R. Di Monte, P. Fornasiero, J. Kašpar, and M. Graziani, “Stabilisation of nanostructured CeO2-ZrO2 solid solutions by addition of Al2O3: a suitable way for production of thermally stable oxygen storage/release promoters for three-way catalysts”, Stud. Surf. Sci. Catal., 140 (2001) 229.
  93. N. Hickey, P. Fornasiero, J. Kašpar, J.M. Gatica, and S. Bernal, “Effects of the nature of the reducing agent on the transient redox behaviour of NM/Ce0.68Zr0.32O2 (NM= Pt, Pd and Rh)”, J.Catal., 200, (2001) 181.
  94. P. Fornasiero and J.Kašpar, "Infra-red study of nitric oxide adsoprtion and conversion on CeO2-ZrO2 mixed oxide", Colect.Czech.Chem.Comm., 66 (2001) 1287.
  95. P. Fornasiero, T. Montini, M. Graziani, J. Kašpar, A.B. Hungría, A. Martínez-Arias, J.C. Conesa, "Effects of thermal pre-treatments on the redox behaviour of Ce0.5Zr0.5O2: isotopic and spectroscopic studies", Phys.Chem.Chem.Phys., 4 (2002) 149.
  96. J. Kašpar and P. Fornasiero, "Structural properties and thermal stability of ceria-zirconia and related materials", in " Catalysis by Ceria and Related Materials", A.Trovarelli, ed., in “Catalytic Science Series” (G.J.Hutchkings, ed.), Imperial College Press, London, (UK), ch.6, pp.217-241, (2002).
  97. J. M.Gatica, P. Fornasiero, J. Kašpar, T. Lesage, S. Aiello, and M. Daturi, "Hydrogen scrambling over Rh/Ce0.68Zr0.32O2 and Rh/Al2O3 catalysts: Effects of support, metal precursor and redox aging", Phys.Chem.Chem.Phys., 4 (2002) 381.
  98. N. Hickey, P. Fornasiero J. Kašpar, M. Graziani, G. Martra, S. Coluccia, S. Biella, L. Prati and M. Rossi. “Improvement of SOx-resistance of silver lean-deNOx catalysts by supporting on a CeO2-containing zirconia”, J.Catal., 209 (2002) 271.
  99. R. Di Monte, J. Kašpar, P. Fornasiero, M. Graziani, C. Pazé, G. Gubitosa, "NO reduction by CO over Pd/Ce0.6Zr0.4O2/Al2O3 catalysts: In situ FT-IR Studies of NO and CO adsorption", Inorg.Chim. Acta, 334 (2002) 318.
  100. J. Kašpar, “Aspetti legislativi relativi alle emissioni da veicoli a motore”, Chim.Ind. (Milan), 84 (2002) 61.
  101. R. Di Monte, P. Fornasiero, J. Kašpar, M. Graziani, C. Manfredotti, G. Martra, S. Coluccia, L. Marchese, P. Ciambelli, M.C. Gaudino, D. Sannino, V. Dal Santo, R. Psaro, S. Recchia, “CeO2-ZrO2-Al2O3 mixed oxides for DeNOx catalysts: Redox properties and catalytic activity”, Chim.Ind. (Milan), 84 (2002) 46.
  102. J. Kašpar and P. Fornasiero, “Nanostructured materials for advanced automotive de-pollution catalysts”, J.Solid State Chem., 171 (2003), 19.
  103. J. Kašpar, P. Fornasiero, G. Balducci, R. Di Monte, N. Hickey, and V. Sergo, “Effect of ZrO2 content on textural and structural properties of CeO2-ZrO2 solid solutions made by citrate complexation route”, Inorg.Chim. Acta, 349 (2003) 217.
  104. J. Kašpar, P. Fornasiero and J.N. Hickey, “Automotive catalytic converters: State of art and perspectives”, Catal. Today, 77 (2003) 419.
  105. J. Kašpar, L .Forni and A. Trovarelli (Eds.), Preface to Special Issue on “VI Italian Catalysis Seminar Giacomo Fauser”, Catal.Today, 77 (2003) 285.
  106. P. Fornasiero, J. Kašpar, T. Montini and M. Graziani, V. Dal Santo and R. Psaro, S. Recchia, “Interaction of molecular hydrogen with three-way catalyst model of Pt/Ce0.6Zr0.4O2/Al2O3 type”, J.Mol.Catal., 204/5 (2003) 683.
  107. G. Balducci, M. S. Islam, J. Kašpar, P. Fornasiero, and M. Graziani. “Reduction process in CeO2-MO and CeO2-M2O3 mixed oxides: A computer simulation study.”, Chem.Mater., 15 (2003) 3781.
  108. N. Hickey, P. Fornasiero, R. Di Monte, J. Kašpar, J.R. González-Velasco, M.A. Gutiérrez-Ortiz, M.P. González-Marcos, J.M. Gatica, and S. Bernal, “Reactivation of aged model Pd/Ce0.68Zr0.32O2 three-way catalyst by high temperature oxidising treatment”, Chem.Commun. (2004) 196.
  109. T. Montini, M.A. Bańares, N. Hickey, R. Di Monte, P. Fornasiero, J. Kašpar, and M. Graziani, “Promotion of reduction in Ce0.5Zr0.5O2: the pyrochlore structure as effect rather than cause”, Phys.Chem.Chem.Phys., 6 (2004) 1.
  110. R. Di Monte and J. Kašpar, “On the role of oxygen storage in three-way catalysis”, Top.Catal., 28 (2004) 47.
  111. P. Fornasiero, A. Speghini, R. Di Monte, M. Bettinelli, J. Kašpar, A. Bigotto, V. Sergo, and M. Graziani, “Laser excited luminescence of trivalent lantanide impurities and local structure in CeO2-ZrO2 mixed oxides”, Chem.Mater., 16 (2004) 1938.
  112. R. Di Monte, P. Fornasiero, S. Desinan, J. Kašpar, J.M. Gatica, J.J. Calvino, and E. Fonda, “Thermal Stabilisation of CexZr1-xO2 oxygen storage promoters by addition of Al2O3: Effect of thermal ageing on textural, structural and morphological properties”, Chem.Mater., 16 (2004) 4273.
  113. R. Di Monte and J. Kašpar, “Nanostructured CeO2-ZrO2 mixed oxides”, J.Mater.Chem., 15 (2005) 633.
  114. R. Di Monte and J. Kašpar, “Heterogeneous environmental catalysis – a gentle art: CeO2-ZrO2 mixed oxides as a case history”, Catal. Today, 100 (2005) 27.
  115. M. Manzoli, R. Di Monte, F.Boccuzzi, S.Coluccia and J.Kašpar, “CO oxidation over CuOx-CeO2-ZrO2 catalysts: transient behaviour and role of copper clusters in contact with ceria”, Appl.Catal.B Environ., 61 (2005) 192.
  116. E. Farnetti, R. Di Monte and J. Kašpar, Homogeneous and Heterogeneous Catalysis in 6.100.Inorganic and Bio-inorganic Chemistry., CHEMICAL SCIENCES ENGINEERING AND TECHNOLOGY RESOURCES, edited by Ivano Bertini, in Encyclopedia of Life Support Systems (EOLSS), Developed under the Auspices of the UNESCO, Eolss Publishers, Oxford ,UK, 2007, [http://www.eolss.net].
  117. R. Di Monte, J. Kašpar, H. Bradshaw and C. Norman, “A rationale for the development of thermally stable nanostructured CeO2-ZrO2-containing mixed oxides”, J. Rare Earths, 26 (2008) 136.
  118. E. Farnetti, J. Kašpar and C. Crotti, “ A novel glycerol valorization route: chemoselective dehydrogenation catalyzed by iridium derivatives”, Green Chemistry, 11 (2009) 704.
  119. C. Crotti, J. Kašpar and E. Farnetti, “Dehydrogenation of glycerol to dihydroxyacetone catalyzed by iridium complexes with P-N ligands.”, Green Chemistry, 12 (2010) 1295.
  120. N. Hickey, I. Boscarato, J. Kašpar, L. Bertinetti, M. Botavina, G. Martra, “Effect of the support on activity of silver catalysts for the selective reduction of NO by propene”, Applied.Catal.B Environ., 100 (2010) 102.